One of the reasons search marketing is so effective is that it delivers information on products and services to people who are actively seeking them out. People enter search terms into a search engine and the engine provides sites and ads that are relevant to the terms. This arrangement is beneficial for the user because they are provided what they want and it's profitable for the company selling goods because their products are put in front of motivated buyers—so the potential for a sale is high.
The success of search marketing hinges on whether the keywords the searcher puts in the query box match the keywords the company has targeted in their online campaigns. If the company selling goods has properly identified the keywords a searcher might use to find products, then there is a good chance a conversion will occur.